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General discussion => Black Powder Shooting => Topic started by: Hawken62_flint on December 28, 2020, 12:19:09 AM

Title: Powder granulation
Post by: Hawken62_flint on December 28, 2020, 12:19:09 AM
Don't know if this is the correct place for this question,  but here it is. I've been collecting the old Dupont oval shaped black powder cans with the paper labels. I recently purchased one that has the powder as "Superfine HFg". Can anyone tell me what the H in HFg stands for?  And what was this granulation used for. Thanks for any info.
Title: Re: Powder granulation
Post by: Robby on December 28, 2020, 07:37:34 PM
hfg represents enthalpy diference beetween gas and fluid and it tells how much heat is needed to change 1kg of boiling water to steam we call it specific heat of evaporation.
en·thal·py
PHYSICS
a thermodynamic quantity equivalent to the total heat content of a system. It is equal to the internal energy of the system plus the product of pressure and volume.
I was curious so I googled a bit. I have no Idea what it means as it relates to powder and when I tried to follow it further I had to swear to something and register to something so I opted out.
Good luck.
Robby
Title: Re: Powder granulation
Post by: D. Taylor Sapergia on December 28, 2020, 08:10:30 PM
Maybe a typo....FFg.  I've never seen black powder with an "H" prefix.
Title: Re: Powder granulation
Post by: Daryl on December 28, 2020, 09:04:43 PM
Interesting that it is on a powder can label. Thus, I wouldn't think of it as a typo. I do not, however, have a better explanation for the "H".
Title: Re: Powder granulation
Post by: Hawken62_flint on December 28, 2020, 09:42:13 PM
It is not a typo, it is on the paper label as HFg. I thought maybe someone older than me might know.  Anyway,  I have added it to my collection and happy to have it even if I never find out what the HF stands for. Thanks to all who replied.
Title: Re: Powder granulation
Post by: D. Taylor Sapergia on December 28, 2020, 10:28:41 PM
Maybe it's like the dot on the coin...could be worth a fortune!
Title: Re: Powder granulation
Post by: Hawken62_flint on December 29, 2020, 01:40:49 AM
I hope you are right. I'll take any reasonable offer over $10,000.
Title: Re: Powder granulation
Post by: Daryl on December 29, 2020, 05:08:34 AM
Don't sell it too short of it's true value.
Just lucky for me I don't collect powder cans. :-\
Title: Re: Powder granulation
Post by: heinz on December 29, 2020, 08:06:37 AM
I have seen the HFg Dupont designation before on red Dupont cans and on some older white labels.  I think they were all Wilmington Delaware labeled cans.  I have not idea what grade or grain size HF was.
Title: Re: Powder granulation
Post by: Marcruger on December 29, 2020, 02:39:43 PM
Where is our Mad Monk when you need him?   :D
Title: Re: Powder granulation
Post by: Daryl on December 30, 2020, 03:06:51 AM
I do hope Bill is well.
Title: Re: Powder granulation
Post by: Mad Monk on December 30, 2020, 06:36:22 AM
I do hope Bill is well.

I am not doing all that well right now.  The MDS killed my immune system.  So they put me on anti-biotics to kill a urinary tract infection.  Very dizzy and sometimes have trouble just thinking.  I never saw the H in the grain designation.  But then the bp cartridge manufacturers had special needs sometimes.  The loading data for one cartridge mfg. had the grain size designations reversed.  Then you had fireworks grain sizes that did match the grain size in a rifle type powder.  So unless you have enough to run through a set of standard screens you never really know.

The term "Superfine" was copyrighted by Du Pont around 1840 when the industry went to a national grain size standard system.  That was used on GOEX cans up until the ownership of the company after the move to Minden. When GOEX closed the old Moosic, PA plant it severed the business relationship between GOEX and the Hagley Museum And Library near Wilmington, DE.  Which is the original Du Pont powder plant turned into a museum and historical site. When GOEX moved to Minden they left almost all of the old Du Pont deigned machinery at Mossic to be sold off as scrap. To that killed the part of the Du Pont to Gearhart-Owens technical backup set up in the original sales agreement.  My old buddy Rob Howard was that technical backup. Then once that happened Rob retired out of Hagley.
Title: Re: Powder granulation
Post by: Daryl on December 30, 2020, 11:26:56 PM
I do sincerely hope you get well/better soon, Bill.
Tks for the notes on the history part of Dupont powder.
Title: Re: Powder granulation
Post by: hanshi on December 31, 2020, 12:34:58 AM
You take care of yourself, Bill; I'm familiar with what a compromised immune system can do.  I hope your health improves quickly so you can be back in fightin' shape.
Title: Re: Powder granulation
Post by: Marcruger on December 31, 2020, 01:58:58 AM
Prayer sent upstairs for you Bill. Best wishes on feeling better in the new year.  2020 has been miserable. God bless, Marc
Title: Re: Powder granulation
Post by: heinz on December 31, 2020, 04:48:06 AM
Some of the od NRA articles from 1900-1910 mention rifle and pistol loads using Dupont Hf powder in 444-40 and 44 special cartridges.  I wonder if it had anything to do with the "flake" process for black powder Dupont patented around 1872.  I speculate that because the flake powder would be outside of the normal granulation size ranges.
Title: Re: Powder granulation
Post by: Hawken62_flint on December 31, 2020, 07:02:42 AM
Sounds like you may have hit on something Heinz. Thanks fo r.c that info.
Title: Re: Powder granulation
Post by: Mad Monk on January 01, 2021, 04:55:18 AM
You take care of yourself, Bill; I'm familiar with what a compromised immune system can do.  I hope your health improves quickly so you can be back in fightin' shape.

Hanshi,

It is terminal.  Just a question of when and how.  I am very lucky. Usually this lack of blood platelets problem causes brain bleeding which would leave me right up there with an anti-gun liberal.
Title: Re: Powder granulation
Post by: Mad Monk on January 01, 2021, 05:03:26 AM
Some of the od NRA articles from 1900-1910 mention rifle and pistol loads using Dupont Hf powder in 444-40 and 44 special cartridges.  I wonder if it had anything to do with the "flake" process for black powder Dupont patented around 1872.  I speculate that because the flake powder would be outside of the normal granulation size ranges.

Heinz,

Up to around 1900 the du Pont that went into commercial .44-40 and .44 special cartridges was there sporting powder made on a special wheel mill at the original plant on the Brandywine near Wilmington.  Then they built a special wheel mill house to run the alterations of their black powder.  Milling nitrate saw dust into the black powder.  You ought to see the difference in the stone construction of that then new mill house compared to the older ones running straight black powder.  I seem to recall that the sporting powder mill was called the Eagle Mill and the powder was sold as du Pont Eagle sporting powders.  Around 1900 they also quit raising their own white willow for charcoal and then went out buying wood chemical plants by-product charcoal that they could buy for about 25 cents a bushel.  Out of the various wood chemicals plants in North Central PA and central Southern New York state.
Title: Re: Powder granulation
Post by: Mad Monk on January 01, 2021, 05:24:54 AM
Some of the od NRA articles from 1900-1910 mention rifle and pistol loads using Dupont Hf powder in 444-40 and 44 special cartridges.  I wonder if it had anything to do with the "flake" process for black powder Dupont patented around 1872.  I speculate that because the flake powder would be outside of the normal granulation size ranges.

Heinz,

If you have an interest in du Pont powders you might want to hit Amazon.  Look for: Lammot Du Pont and the American Explosives Industry 1850 - 1884 by Norman B. Wilkinson.  It is a wealth of information on the black powder business and how Du Pont operated their operation.  They sure did not put a leash on Wilkinson when he wrote it.  After the Civil War Lammot formed what became as the Powder Trust.  This is when he and some of the other big powder companies dealt with the large numbers of small family owned and operated small powder plants scattered around the hard coal region of Eastern PA.  Brutal !!!  Lammot as the first du Pont male to get something akin to a college education.  And his driving force was to constantly increase pounds per man hour of blasting powder used in coal mines.   Amazon price on the hardcover is $19.95.  You can't go wrong with that if you really want to see the black powder production industry when it was at its peak and how cut throat the companies could be in their business.

Bill K.
Title: Re: Powder granulation
Post by: heinz on January 03, 2021, 02:25:41 AM
Bill, I should have been clear that the NRA articles weRe talking about handloads in 44 caliber using Hf powder.  I do not know if DuPont was using it in their commercial loads. 
I am ordering the book.  I find the robber baron era fascinating.  Greed personified.
Title: Re: Powder granulation
Post by: Mad Monk on January 03, 2021, 06:28:40 AM
Bill, I should have been clear that the NRA articles weRe talking about handloads in 44 caliber using Hf powder.  I do not know if DuPont was using it in their commercial loads. 
I am ordering the book.  I find the robber baron era fascinating.  Greed personified.

I was able to get into Hagley Museum and Library records on old powder cans in their collection.  Still could make no sense out of the HF grain size designation.  They show in their collection an Indian brand Rifle HF.  Then a number of Hagley Mills HF cans.  But nothing noted with the photgraphs of the cans as to why the use of H in the grain size designation.  And then still used the "superfine" on the labels which makes them clearly straight black powder.  The Superfine copyright applied only to their black powders and not with any of their semi-smokeless or smokeless powders.  Then used a host of other names on various types of black powder for small arms use.  If a batch of rifle burn rate powder did not pass standards they simply packed it as a shotgun powder brand.
Title: Re: Powder granulation
Post by: hudson on January 05, 2021, 07:28:31 PM
Bill, best wishes with your health problems. It is always nice to hear from you I very much enjoy your posts.
Title: Re: Powder granulation
Post by: sa_handforged on January 08, 2021, 04:58:30 PM
Mad Monk:
new to the Forum, I enjoyed reading this post and your deep knowledge. I also remember visiting the Hagley several years ago and that beautiful DE countryside.
I will seek to pick-up a copy of that Wilkinson book, as sounds highly informative; thank you again !

sending prayers for your health
Title: Re: Powder granulation
Post by: Mad Monk on January 14, 2021, 07:15:48 AM
Don't know if this is the correct place for this question,  but here it is. I've been collecting the old Dupont oval shaped black powder cans with the paper labels. I recently purchased one that has the powder as "Superfine HFg". Can anyone tell me what the H in HFg stands for?  And what was this granulation used for. Thanks for any info.

I was digging through some boxes of old shooting pictures tonight and ran into 3 reproduction du Pont post cards that date back into the mid to late 1800s.  One shows a shooter shooting at a woods buffalo that used to live in the woods here in the East.  Various size containers of Du Pont black powder.  The tn cans tell me the post cards would date bck to after the U.S. Civil War.  The labels state "HFg".  The back of the post card states: DU PONT's GUNPOWDER - Early advertisement of sporting powder.  Lithograph from the collection of the Hagley Museum.  Then there is a different post card with nobody shooting different views of different areas.  But again a pile of powder containers up to large wooden kegs marked with the HFg labels.
Title: Re: Powder granulation
Post by: Mad Monk on January 14, 2021, 07:43:03 AM
Don't know if this is the correct place for this question,  but here it is. I've been collecting the old Dupont oval shaped black powder cans with the paper labels. I recently purchased one that has the powder as "Superfine HFg". Can anyone tell me what the H in HFg stands for?  And what was this granulation used for. Thanks for any info.

I was digging through some boxes of old shooting pictures tonight and ran into 3 reproduction du Pont post cards that date back into the mid to late 1800s.  One shows a shooter shooting at a woods buffalo that used to live in the woods here in the East.  Various size containers of Du Pont black powder.  The tn cans tell me the post cards would date bck to after the U.S. Civil War.  The labels state "HFg".  The back of the post card states: DU PONT's GUNPOWDER - Early advertisement of sporting powder.  Lithograph from the collection of the Hagley Museum.  Then there is a different post card with nobody shooting different views of different areas.  But again a pile of powder containers up to large wooden kegs marked with the HFg labels.

To add to this.  That suggests to me that the "rifle" powder shown was the equal mixture of 3F and 2F grain sizes.  I had seen this in other powder company cans marked as a rifle powder but not grain size on the label.  When I pulled the powder out of boxes of original load BP cartridges I found the same thing.  Then some comments found in Capt. Mordecai's work at Washington Arsenal in 1856 shows the uses of this granulation mixture.  I had all of the stuff in the lab to do screen analyses.  That was all part of my daily work.  So when the boss was not around I would do screen analyses on some of the old black powder samples I had collected.  At that time the military used an equal mix of 1F and 2F as a musket powder for the big .69 caliber smooth bore muskets.  When they made up lads for the 1842 Mississipi Rifle they used the 3F and 2F mix of grain sizes.  When the arsenals developed the minie for the Civil War Mordecai told them to use straight 1F in the charges for that gun.  So chances are that du Pont called the rifle powder grain mixture as this "H" designation.
Title: Re: Powder granulation
Post by: hanshi on January 14, 2021, 10:34:45 PM
My best wishes for your health, Bill.  Your situation is very concerning and very disturbing news for us.  We all sincerely hope for the best outcome.
Title: Re: Powder granulation
Post by: Mad Monk on January 14, 2021, 11:47:06 PM
My best wishes for your health, Bill.  Your situation is very concerning and very disturbing news for us.  We all sincerely hope for the best outcome.

Hanshi,

I don't get all hyper about it but this bone marrow failure, MDS is always terminal at my age.  I will shortly be 79 years old.  Too old for a bone marrow transplant.  It took 45 years for the butadiene in the chem plant to catch up with me. Almost all of those I worked with, younger and older are long gone from the results of handling twenty different chemicals in the reactor building I worked in. When you work with that number of carcenogenic chemicals without proper safety gear you are lucky to see retirement at 65.  So I have spent a lot of years bracing for this and dealijg with it.  I mean after 30 years of going to work and punching in wondering if you would finish the shift in the same county and in one peace you develop that "oh well" mentality.  So the whole idea of this really does not trouble me and I'll just keep plugging along until it happens.  I joke with the nurses in the Infusion Unit that the only thing keep me going is the fact that the devil has a restraining order out on me.  But you concern is certainly appreciated.  On this message board I have run into a lot of nice guys which are a welcome relief from life her in the center of this city.
Take Care, Bill K.
Title: Re: Powder granulation
Post by: smylee grouch on January 15, 2021, 12:33:34 AM
Hi Bill: I think you have a great attitude and that can carry you on. Please know how much we all respect your contributions and opinions on this forum. We wish you the very best and gratefully thank you for you shared knowledge. Smylee Grouch  :)
Title: Re: Powder granulation
Post by: Daryl on January 15, 2021, 04:35:25 AM
Bill- you  and your perseverance are indeed, a beacon for us to follow.
We all love and appreciate your posts.
You, Bob Roller & Dennis are heroes to us all.

LOL - so are all the rest of you old !@#$%. ;D
Title: Re: Powder granulation
Post by: heinz on January 15, 2021, 04:52:14 AM
Bill, excellent hypothesis on the Hf granulation.  That would fit in well with its use in heavy 44 Special loads in the early 1900s.  I have played with my 45 Colt using 5 grains of 4f and then filling the case with 2f then compressing the load and crimping the bullet.  Makes a fun load.  I will have to try mixing 2f and 3f for a load this year when it warms up a bit.
Title: Re: Powder granulation
Post by: Mad Monk on January 15, 2021, 05:32:18 AM
Bill, excellent hypothesis on the Hf granulation.  That would fit in well with its use in heavy 44 Special loads in the early 1900s.  I have played with my 45 Colt using 5 grains of 4f and then filling the case with 2f then compressing the load and crimping the bullet.  Makes a fun load.  I will have to try mixing 2f and 3f for a load this year when it warms up a bit.

If you send me your E-mail address by PM on the board I could scan in the two post cards and send them to you if you want.  What gets me is that I bought them a bit over 20 years ago at Hagley.  Looked at them several times and the HFg blew right by me.  And that label was on everything in the post cards from small cans up to a big wooden keg of powder.  I spent a lot of time discussion standard grain sizes (screen sizes) when I was dealing with Rob Howard at Hagley.  We even talked about the mixed grain thing but I never though to ask how they labeled that.  But in the post cards they show the copyright " Superfine" and the "Rifle" powder.  Doesn't leave anything to explain the "H".  These post cards are the old real fancy artwork.  Getting old I forgot the name they give that artwork.  Right now we are joking about having to get a municipal burn permit for my birthday cake candles.