Guys,
I have rifled a "Whitworth" barrel - a 7 sided polygon rifled bore. It was a lot more time consuming than the typical 7 round bottom grooves. You have to remove a lot more metal! It was fun and entertaining, but no advantage. Oh, by the way, it was a pistol barrel.
Just used a different shaped cutter for the rifling head with wide, shallow teeth rather than the regular round topped teeth. It was a lot longer to cut - it looked really neat and a good conversation piece - it did not shoot or load any differently than a regular barrel - probably I will not do it again. I just used a regular patched ball, not a special bullet.
Jim