Rifling with square groove bottoms, particularly Gm and Goodoien barrels have about .010" to .012" deep rifling. Barrels with round bottom grooved rifling will normally have .016" to .025" deep rifling. The deeper the rifling, the heavier the patch must be. A load that proves accurate in a barrel with .012" deep rifling, will be about .004"(thickness of patch) too loose for best results in the deeper rifling.
With the .36 cal rifle, I'd be inclined to shoot at about 35 yards for accuracy testing, and with .40 cal or larger, move that out to 50 yards. I've found accuracy tests at close range to be useless for determining a loads accuracy for developing loads. The larger bores will group incredibly tight at close range, but spread even by 50 yards. It is disheartening to shoot a 2" group at 25 yards with your rifle, only to have someone then shoot a 1" group at the same range, using his smoothbore. I know, been there - me shooting both guns.
The round bottomed rifling loads more nicely than square - IF both loads are tight fitting and both loads do not allow the accumulation of fouling.
If round bottomed rifling gave as good accuracy as square bottomed rifling, due to the easier cleaning and loading, round bottomed rifling would be used for target or match barrels - they aren't. I think the difference might be small, but small diferences are what wins matches.
(my) Rules of thumb :- .005" under ball for square rifling + .018" to .022" patch
-----------------------------.005" under ball for round rifling + .022" to .025" patch