I would not weld on the frizzen it is hardened and tempered. If you notice on the bottom of the frizzen
next to the barrel there is a little notch cast into the bottom. That is where I put my touchholes, scribe a line across the top of the pan and the center. You are only 1/32 or so high, it will be just fine.
Black powder burns at 4000 deg but it only takes 400 deg to ignite, the heat from your pan powder will set the main charge off faster than a low touchhole burning through like a fuse.