Don,
Ampco is indeed a company that makes alloys of copper. Many contain iron, aluminum, and tin in small amounts to improve one mechanical characteristic or another. However, they also make a family of alloys that include cobalt and beryllium (up to about 2%). The beryllium makes for an incredibly strong alloy that still retains excellent thermal conductivity. I have made liners out of the beryllium alloy and they hold up as well as any of the stainless steel liners I have used. In the rocket business, we use beryllium copper for a lot of things because the increased thermal conductivity allows the alloy to maintain strength at high heat flux because the heat is being absorbed by the mass of the material. The erosion in your case is undoubtedly related to the thickness (or thinness) of the edge of the flash hole and also which Ampco alloy was used to make the liner. (Ampco makes 30 or so different alloys).
Taylor,
The liner may or may not have some beryllium in it, but it is certainly not made of solid beryllium. Solid beryllium, although a metal, will shatter like glass in thin sections. Just 1 or 2 % beryllium added to copper is used to make very strong, non magnetic tools that are used in the explosives industry and military ordnance assembly and disposal applications. I have added 1% beryllium to silver to make a very strong silver alloy that has a unique characteristic....it will never tarnish.