I agree on the rifle. I particularly like what looks like a lightened area of wear at the wrist. I just love to see well used rifles- dents, dings and warts included. It just seems more honest than a flawless museum piece.
Speaking from personal experience, that's a good elk load but probably not a 100 yard load. But recognize that in my mind there's no such thing as a 100 yard elk load with a 54 cal PRB. A 58 cal comes closer, but I just don't like longer shots at large animals. Personal prejudice. The biggest problem in my mind is accurate range estimation, and the difference between an 90 yard elk and a 120 yard elk is hard to see, especially in low light. Yet that much sighting error can be a big deal when shooting at a target as small as a heart.
As for power, yeah. I'd hunt with your load out to between 50 and 75 yards. A relative's identical rifle and similar load has proven itself with two one-shot kills on elk at that range. With my own GPR 54 cal I shoot either 90 grains of Geox 3f or Pyrodex P. Reliable killer as far as I'm willing to shoot (i.e., 75 yards).
As for hunting differences between Pyro P and Goex, I don't find any for the first few shots from a clean gun. Pyrodex is only a problem with repeated shots, manifested as slower ignition and eventually slight hangfires after half a dozen shots or so. In my experience it happens quicker with drum bolsters than with patent breeches, but it's honestly a factor with both. In general I've had better luck using Pyrodex P than RS with drum bolsters.
The eventual ignition problems are certainly an issue with a range gun, but not with a hunting gun. The distinction is important for a traveling hunter due to the inability to fly with either powder and the requirement to locate sources at your destination. You can generally find Pyrodex with little effort, but you have to do your homework and make arrangements beforehand to acquire black. Not a religious issue with me.