I am sure there are limiting factors. As powder increases you'll get a proportional increase in velocity. Then, at some given charge you'll notice that the velocity gain was less than expected for the increase in charge. This is known as the Point of Diminishing Returns (PODR). For example say you get 100 fps gain every time you increase the charge by 10 grains. Until finally going from 80 to 90 grains the velocity only increases 50 fps.
My hypothesis for the board would be that (for black powder) increasing the barrel length will push that PODR up for a given caliber. In other words say my above example was for a 28 inch barrel; if you increased the barrel length to 36 inches you might get a 100 fps gain going from 80 to 90 grains, but hit the PODR going from 90 to 100 grains. And a 42 inch barrel might be able to digest a 110 grain charge before encountering the PODR.
I'm sure there's a point where the barrel just flat-out gets too long, but this probably is not experienced in a practical-length gun barrel.
I am fairly certain that the point of diminishing returns relates to the burn rate of the powder in a particular size bore.
To better explain that.
If you look at original rifles that still have the original tin charger you see in something like a .44 caliber you have a gunsmith made tin charger that throws just about a grain per caliber. Roughly 45 grains for a .44 or .45 caliber rifle. These guns were usually shot using a very fast burning sporting powder at that time.
Most of the data out there now was generated using du Pont and then GOEX black powder. If you look at a can you see it described as a "rifle" powder.
If you go back to the 1800's. Up until the end of the Civil War you see three distinct types of black powder being produced for use in small arms. You had a very fast, very hot burning sporting powder. Used mainly in the guns up to .50 caliber. Above .50 caliber you would see a "rifle" type powder being used. At .58 caliber you would see a "musket" powder being used. Each powder fit into a specific burn rate range. And by burn rate as it applies here it refers to the actual combustion of the powder separate from any grain size considerations.
The differences between the 3 types related to the "quality" of the ingredients used and the length of time they would be run in the wheel mill.
When the Swiss sporting burn rate powder first came onto the U.S. market I looked at it in my .45 caliber patched ball rifles. It showed this point of diminishing returns around 43 to 44 grains in the .45. In the .50 caliber patched ball rifle it was around 55 grains.
Basically, a sporting burn rate powder gives this p.o.d.r. at about 1 grain per caliber. A rifle powder around 1.5 grains per caliber and a musket powder around 1.6 grains per caliber.
The old writings on black powder mention what they called the "expansive force" in a powder charge. The very fast, very hot sporting powders gave the most expansive force per unit of weight. A rifle powder gave less expansive force and a musket powder even less of this expansive force.
If you shot a musket burn rate powder in a .36 caliber you had to use a lot of it to get a workable velocity with a lot of bore fouling as a result. At the same time if you tried to shoot the very fast, very hot sporting powder in something like a .69 caliber musket it would really hurt the shoulder and give you a lot of blow by in the gun. They tailored the chemical burn rate of the powder to more or less match the projectile mass being used. Balancing the volume of gases produced. The rate at which they are evolved by the burning powder and the temperature of the gases evolved. All of this added up to this expansive force thing.
This p.o.d.r. thing is even seen in the early bp cartridges. The original .45-70 cartridge was designed around Civil War surplus musket powder. NOT a rifle burn rate powder. So the p.o.d.r. in a .45 with a musket burn rate powder is 70 grains. The cartridge originally designed around the rifle burn rate powder was a .45-60. The oriinal .44-40 artridge was designed around the very fast sporting powders of the day.
Bill K.