Daryl,
It's the same teflon that is used on a cooking skillet. You have to get it really hot for quite a while to make it out gas. If you can cook and eat off of it safely, you can shoot it away safely. I make a pyrotechnic rocket motor igniter that uses a compound of powdered teflon and powdered magnesium which burns very hot. In that case, since the teflon is actually consumed in the reaction, you get out gassing that is not good to breath. But I would not worry about whatever minute amount of teflon is on the patching.