I don't know who makes a straight groove smoothbore barrel as a normal stock item ahead of time...wouldn't think anyone would due to what I assume would be a virtually non-existent market for them in the big picture scheme of things.
If someone was purely interested in just improving PRB accuracy, thy would have had it grooved with actual rifling grooves.
You didn't mention groove depth...I think the groove depth could reveal a lot as it would determine if there might be any appreciable gas blow-by...if shallow enough I suspect there could be enough wad expansion from the gas pressue at set back time to fairly well seal the bore, certainly from a practical usability point of view.
Leading me to speculate that someone had that barrel made (or it was a smoothbore and they had the straight grooves added) in an effort to improve round ball accuracy some which straight grooves will do...but was counting on the shallow grooves to still allow the barrel to be used for shot loads like a smoothbore. And if they are really shallow, leading may not be much of a problem at all.
If you have a mic or caliper, it would be intersting to try and measure the groove depth.