My .32 has a 48" twist. Unlike perhaps many guys with these little calibers, I actually tested mine at 50 and 100yards to find loads that would work at longer than point blank ranges.
With only 20gr.of powder, this littlest flinter (on my rack) will put 5 consecutive balls into a .36 calibre hole-however, that load opens to 2" to 2 1/2" at 50 yards due to spreading grouping and fliers. Upping the powder charge to 30gr., closes the groups to 1 1/2" at 50, and another 5gr. at 35gr. closes them further to 1"- again, at 50 yards. 40gr. opens the groups back up to 1 1/2", so I stay with 35gr. for all shooting. As with most of my guns, zero'd at 25 is also zero'd at 50.
I didn't try 40gr. charge at 100yards, however 35gr. did give me a nice round, 3" group at that range. The next time I shot at 100yards, I was rewarded with another 2 3/4" to 3" group. I have since increased the thickness of the patching to .025", but haven't paper tested that load yet. My rate of hitting on the long range gongs on our bush trail has increased, so I feel it shoots a bit better than the thinner, .020"ticking or .0225" denim patch. The only way to make sure, is to bench test on paper, of course.