It is simply easier to get match-grade, under 1" groups at 50 yards using pure lead bullets that allow even tighter loading which usually provides better accuracy. I have never seen the reverse occur.
You may be right that it's easier to reach the ultimate in accuracy with pure lead. I don't have to worry about that. Nevertheless, I believe WW balls can shoot exceedingly well. The fellow who put me on to using WWs is the founder of Cast Performance Bullet Co. He told me, "I once shot 4 balls into 1 1/4" at 100 yards with a 54 cal FLINTLOCK over a rest, and I did it with WW balls."
I plan to use my flintlock on elk this October and was concerned that my pure lead balls would be too soft. Here's what one did inside a relatively small bear. It lodged under the far side skin. That sounds impressive till you see how much a bear shrinks when you take his pajamas off.
With an elk being larger and tougher, I want more penetration. This guy knows of 6 elk taken with .490 patched round balls with only 1 ball recovered! All the rest passed clean through. That's why I learned to cast and why I chose WW lead.
As I mentioned in my note on the other thread, no one has ever mistaken me for a marksman, so I'm pretty happy with how well the WW balls shoot.