I wish someone would do a chemical analysis of those great powders. The only thing I can think of that might be different is the charcoal, or the processing. Unless of course the proportion are different too...
Albert
This is really Mad Monk's territory but here goes...
The better powders, the faster ones, used about 76% Potassium Nitrate rather than 75% or less.
This, coupled with proper charcoal and milling made for a fast chemical burn rate.
They then pressed it, broke it and final dryed the powder by tumbling it.
This helped remove sharp edges from the grains (which helped control initial burn rate) and some of the KNO3 to migrated to the surface with the water forming a hard shiny finish that also helped control the initial burn rate. Cheap powders used graphite for polish.
The key is charcoal made from the proper wood to a certain creosote content and absolutely pure KNO3 and sulfur. Long milling times compared to blasting or other low grade powders and overall care in making the powder. The real magic was in the purity/suitability of ingredients and the time and care taken in making the powder.
For example distilled water is a must, anyone remember the GOEX made some years ago with all the dust in the cans? Untreated ground water was the cause. Impure saltpeter can slow the burn AND make the powder suck up too much water from the air which also slows the burn rate.
Blasting powders were often made with sodium nitrate. ANY amount of this in a propellant powder is a disaster so propellant powders, the god ones anyway were made in a separate plant or unit than sodium powders. Blasting and low grade powders had a shorter milling time, much shorter in many cases. This resulted in a poorer mix of ingredients and a larger particle size which reduced performance in firearms. If the charcoal is too hard, often made from the wrong wood for a premium powder, it will not breakdown easily and the creosote level may be too low if its the wrong wood or burnt too long in the charcoal making process and/or not made by the retort method which gave much better control of the process.
Swiss powder is the only premium powder available right now.
The others are also rans. However, Goex is better now than it was when being made at Moosic, for several reasons. But its still not Swiss. Any of the better powders available today are superior to the powder used by many Americans in the 18th century. Some of which was unpressed powder granulated by being pressed through a screen by hand.
Daryl's American Dead Shot was pretty good stuff from the 19th century writings.
While Dupont might have been readily available to Frank Mayer this does not make it a "leading powder". It just made it commonly available.
Dan