You may be led astray by all of the odd calibres found in old guns. These odd calibres were created by freshing a barrel.
They would work on the bore with a lap and cutters inserted into them until the bore looked good. They would then
make a mould for that gun, and they were not really concerned about the actual bore size. As far as new barrels go,
I don't know of any that are deviating from the "standard" 32, 36, 40, 45, 50, 54, 58, 60, & 62. From a cost standpoint
it is not feasible to make an oddball calibre. To do so might require a new drill, reamer, and rifling head, these are not
nickle and dime items.............Don