Borrowed from the Hallowell and Co. Illustrated Firearms Dictionary.
"Cast Off - An offset of a gun stock to the right, so that the line of sight aligns comfortably with the right eye while the butt of the stock rests comfortably on the right shoulder. Almost all right-handed shooters benefit from a little castoff and most custom built guns are made this way. The only question is how much. The castoff of a gun is about right when, with the gun comfortably mounted, the front bead lines up with the center of the standing breech. A stock offset to the left, for shooting from the left shoulder is said to be Cast On.
See also: Eye Dominance."