Thanks Dan - we are all indebted for your explanation of these powders.
IIRC from Firearms of the American West, this is concerning the US powder quality improvement in their Military ctgs. In the 1700's into the early 1800's, the powder was weak indeed and the standard charge for the .69 musket ctgs. was 165gr. which included 4 to 6gr. for priming as the pan was primed and hammer closed before loading the barrel.
After the development of more highly refined powder(in and around 1820?), the issued ctg. charge for the .69 army Muskets was reduced to 135gr. including the prime. This newer powder gave the same ballistics as the old charge had produced prior to the powder improvement.