Ridge,
Typical plumbing solder "used to be" a 50/50 tin-lead mix.
While the "electrical solder" per the 'mil-spec' I used to work to was a 60/40 mix of tin to lead.
The flux used normally had the greatest bearing on what each was used for.
Acid fluxes for most 'general' work and rosin (non-corrosive) fluxes for electrical work.
You can use 'bailing' or 'tie' wire to hold the parts in place and once the solder starts to flow just give it a little extra twist.
You can also buy (Brownells) or make (C-clamp and hacksaw blade) a "Front Sight Soldering Fixture" that will not draw a lot of heat from the joint.
Check out Brownells and you tube.
As mentioned above, "Soft Solder" has been and is used for gun building.
It has been used for a loooong time so if your joints are properly tinned and sweated, you should be fine.
Cheers,
Smoketown