A lot depends on th degree of finish on the horn. Is it simply scraped smooth, sanded smooth, or machine polished. Each will require a different process to give it an aged appearance. The one that works best for me on horns that have at least some white, or cream, coloration is Lincoln medium brown shoe dye. I brush it on quite heavily, and then immediately rub it back with a wet rag. Be sure to get Lincoln brand dye, Feibing's does not play well with the wet rag, and tends to be blotchy.
I usually seal the dyed surface with clear flat, or semigloss, artist acrylic clear used to seal acrylic paintings.
Hungry Horse