Paleo Man Jim is a great source of free knapping instruction on youtube. Although he only really teaches tool knapping, I'm fairly confident one could make gunflints after learning the basics from Jim.
Personally started to try, as there is no rock on my ridge that doesn't spark when struck, but there's also NUNNOVIT suitable for making gunflints. It all has inclusions and such that ruin every piece. I've don't even look anymore. Start with the right stuff, hope you find it local, but also you can buy spalls online.
But it is wonderfully neat to bang and shape rocks into tools/parts same as they did for thousands of years.