Author Topic: Is there a return from Iron Nitrate gone too dark ?  (Read 3104 times)

Offline HarmsWay

  • Starting Member
  • *
  • Posts: 3
Is there a return from Iron Nitrate gone too dark ?
« on: December 27, 2023, 10:11:54 PM »
I recently acquired a nice half stock .40 built in the 1960's... It's a very well built rifle. However,.. The curly maple stock is very,very dark. I might be wrong, but I believe that it was treated with Iron Nitrate, And possibly never neutralized (which is an assumption on my part)... If you hold it in the right light, You can see the maple has a high level of character, But its so dark, it almost looks black.
I built several rifles back in the day, and actually used Iron Nitrate to enhance the grain... But I never had to fix the effects of a stock getting so dark before. Although I still do a lot of firearms repair.... I figured, I better get advice from some others that have crossed this bridge before...

Thanks in advance for any advice that may help....
With best regards.









Eph. 2:8-9... A sinner saved by grace

Offline rich pierce

  • Administrator
  • Hero Member
  • *
  • Posts: 19520
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #1 on: December 27, 2023, 10:18:02 PM »
It’s usually skin deep. It’s a lot of work but you could work the whole gun over with steel wool.
Andover, Vermont

Offline Jim Kibler

  • Hero Member
  • *****
  • Posts: 4473
    • Personal Website
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #2 on: December 27, 2023, 10:19:13 PM »
I'd expect you would have to sand it back.  You could then over coat with aniline dyes to adjust.

Offline D. Taylor Sapergia

  • Member 3
  • Hero Member
  • *
  • Posts: 12671
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #3 on: December 27, 2023, 10:47:48 PM »
I agree with Jim.  I'd sand that stock with blocked sandpaper.  The curl in the wood will remain black and the sandpaper backed with a piece of spruce or the like, will take the stain off the tops of the mountains, leaving a very pleasing stain.  Steel wool will exaggerate the rippled surface of the stock and will likely not be aggressive enough to take away much of the black.
D. Taylor Sapergia
www.sapergia.blogspot.com

Art is not an object.  It is the excitement inspired by the object.

Offline Mike Brooks

  • Hero Member
  • *****
  • Posts: 13415
    • Mike Brooks Gunmaker
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #4 on: December 28, 2023, 12:44:27 AM »
I'd probably try a purple scrubby first to see what happens.
NEW WEBSITE! www.mikebrooksflintlocks.com
Say, any of you boys smithies? Or, if not smithies per se, were you otherwise trained in the metallurgic arts before straitened circumstances forced you into a life of aimless wanderin'?

Offline Daryl

  • Hero Member
  • *****
  • Posts: 15822
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #5 on: December 28, 2023, 04:23:10 AM »
I expect Mike is talking about purple Scotch Brite.
Daryl

"a gun without hammers is like a spaniel without ears" King George V

Offline Matt Evans

  • Starting Member
  • *
  • Posts: 29
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #6 on: December 28, 2023, 07:15:33 AM »
I like them dark, but ya that one is a bit to dark. I would start on the wrist and forend and maybe a bit on the cheek of the stock, in the areas that would be handled and wear the finish. Definitely use a finer abrasive material. I’m also thinking scotch pad and elbow grease. Maybe if the scotch pad isn’t cutting it some steel wool or 2000 grit wet dry paper.

Offline Dphariss

  • Hero Member
  • *****
  • Posts: 9920
  • Kill a Commie for your Mommy
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #7 on: December 28, 2023, 08:31:07 PM »
I would try rottenstone and linseed oil as a carrier. It should bring the color back with out too much wood removal and a very smooth finish.
The stain was probably a store bought “Aqua fortis” that is adulterated with hydrochloric OR they did not make the stain right or just used  acid and never did a baking soda wash or they added iron but not enough to deplete the acid properly. Properly made ferric nitrate will not do this. Its color fast.
He who dares not offend cannot be honest. Thomas Paine

Offline P.W.Berkuta

  • Hero Member
  • *****
  • Posts: 2213
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #8 on: December 28, 2023, 09:10:23 PM »
I got a rifle stock that color and it's with the same AF that I have been using for years. I got the AF from Eric Kettengburg and I believe it was a 6/1 ratio.
I've used it on many maple guns and this one is the only one that it turned black. I think it was the wood's mineral content that caused it. When the stock was blushed with a heat gun it turned immediately dark and when I applied the oil finish it went black. The color grew on me and I left it as is.
"The person who says it cannot be done should not interrupt the person who is doing it." - Chinese proverb

Offline HarmsWay

  • Starting Member
  • *
  • Posts: 3
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #9 on: December 28, 2023, 09:47:09 PM »
Thanks for all the suggestions so far,... Keep those ideas coming !.... I have several arms on the repair rack I'll have to get to first, As well as a quick trip south for a week. So I wont get into this one until late January. I think I'll start with the least invasive process, in the least conspicuous place I can find.... Then proceed until I can find a suitable solution. Worst case scenario,... It stays dark.. And I'll give you a range report in the spring...

But please keep those suggestions coming !

Thanks guys, and as always.
Best Regards     
Eph. 2:8-9... A sinner saved by grace

Offline P.W.Berkuta

  • Hero Member
  • *****
  • Posts: 2213
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #10 on: December 28, 2023, 09:53:54 PM »
I just took a picture of the rifle that I posted above - it's on my wall - I enhanced the pictures a bit using the computer.




"The person who says it cannot be done should not interrupt the person who is doing it." - Chinese proverb

Offline Mike Brooks

  • Hero Member
  • *****
  • Posts: 13415
    • Mike Brooks Gunmaker
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #11 on: December 29, 2023, 02:20:07 AM »
All the guns I built years ago and used Wakon Bays's Aqua Fortis on are now black, neutralized or not.
NEW WEBSITE! www.mikebrooksflintlocks.com
Say, any of you boys smithies? Or, if not smithies per se, were you otherwise trained in the metallurgic arts before straitened circumstances forced you into a life of aimless wanderin'?

Offline shootrj2003

  • Starting Member
  • *
  • Posts: 30
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #12 on: December 29, 2023, 03:10:44 AM »
How about Ajax with bleach applied with a grey scrubby from auto body parts 800 grit equiv. It’s only a little to dark…!

Offline shootrj2003

  • Starting Member
  • *
  • Posts: 30
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #13 on: December 29, 2023, 03:42:28 AM »
Or wood bleach,used with caution,don’t want to go too far,that’s doubtful as dark as that is,but I d use it with care..it’s also quite hazardous,eyes ,breathing etc. The thing is the finish -oil varnish,laquer wax,etc.,will shield the color and needs to be removed if you don’t remove it all it will shield leaving dark areas.chemical removers will prevent changing profiles and lines, but have their problems.
« Last Edit: December 29, 2023, 03:57:57 AM by shootrj2003 »

Offline Mike Brooks

  • Hero Member
  • *****
  • Posts: 13415
    • Mike Brooks Gunmaker
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #14 on: December 29, 2023, 03:49:18 AM »
Wood bleach?
NEW WEBSITE! www.mikebrooksflintlocks.com
Say, any of you boys smithies? Or, if not smithies per se, were you otherwise trained in the metallurgic arts before straitened circumstances forced you into a life of aimless wanderin'?

Offline shootrj2003

  • Starting Member
  • *
  • Posts: 30
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #15 on: December 29, 2023, 04:13:15 AM »
Yes there is three ways ,laundry bleach,the least effective,or woodworkers bleach based on oxalic acid bought a hardware stores in powder form,and real strong stuff and an,expensive ,two part bleach, a mix of lye and hydrogen peroxide you mix from bottles .my guess would be the hardware store bleach would do the job nicely providing you get the finish off,it’s pretty good stuff but gloves ,face mask and ventilation would be a real good idea,it stinks and can burn ,if you follow precautions,you’ll be fine.if you know of a good woodworker he may do it for a small fee.

Offline Top Jaw

  • Hero Member
  • *****
  • Posts: 575
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #16 on: December 29, 2023, 05:42:53 PM »
Since it’s already this dark, I like the suggestion of rubbing back or sanding back the wear areas first (or more).  And possibly stopping short of doing the entire stock end to end to a uniform level.  That would be more appealing in this case - at least to me. 

In my limited experience with smaller projects, and depending on the type and depth of the finish used,  very fine sandpaper (400 or 600 grit) may likely become the best method in the end to get through both the finish and the AF stain - unless your also after a good upper body workout. 😀. If it’s a thinner linseed oil finish from back in the day, less aggressive methods should work. 

Offline Mike Brooks

  • Hero Member
  • *****
  • Posts: 13415
    • Mike Brooks Gunmaker
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #17 on: December 29, 2023, 06:00:12 PM »
Fine sandpaper will clog up with finish quickly.
NEW WEBSITE! www.mikebrooksflintlocks.com
Say, any of you boys smithies? Or, if not smithies per se, were you otherwise trained in the metallurgic arts before straitened circumstances forced you into a life of aimless wanderin'?

Offline Jim Kibler

  • Hero Member
  • *****
  • Posts: 4473
    • Personal Website
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #18 on: December 29, 2023, 07:32:21 PM »
Pumice or the maroon scotchbrite may work.  Worth a try.  Mineral oil (baby oil) will help in the rubbing back process.  You can also use mineral on the sandpaper if you are having difficulty with clogging.  I would try 320 grit or 400 grit sandpaper.  If you come back with dye stains, they won't care about the mineral oil.

Jim

Offline Tim Crosby

  • Administrator
  • Hero Member
  • *
  • Posts: 18385
  • AKA TimBuckII
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #19 on: December 29, 2023, 07:51:27 PM »
Wood bleach?

   Oxalic acid, I have used it to lighten aged wood, like a deck darkened with age but never on a stained/finished piece. White vinegar will do about the same.

   Tim

Offline Scota4570

  • Hero Member
  • *****
  • Posts: 2393
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #20 on: December 29, 2023, 08:09:53 PM »
I agree with Jim.  I bet it will really pop if rubbed back.  This is the one place I use BLO diluted with solvent. 

Offline J.M.Browning

  • Full Member
  • ***
  • Posts: 179
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #21 on: December 29, 2023, 08:20:45 PM »
Just choose one of many abrasive products - take as much black out as you desire - its really not that difficult . Just carful so the metal does not stand proud when you are done .



Thank you Boone , Glass with all the contemplate I read with todays (shooter's lightly taken as such) , you keep things simple .

Offline Dphariss

  • Hero Member
  • *****
  • Posts: 9920
  • Kill a Commie for your Mommy
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #22 on: December 30, 2023, 06:49:42 AM »
Another way, besides the rottenstone, is to wet sand with fine wet or dry paper 600 or finer even 1500. Using boiled linseed as the wetting agent. I have used both ways on stocks that were too dark. The wet or dry paper is the best for one this dark I think.
He who dares not offend cannot be honest. Thomas Paine

Offline Jerry V Lape

  • Hero Member
  • *****
  • Posts: 3028
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #23 on: December 30, 2023, 09:45:33 AM »
I had a stock go black when blushing the aqua fortis.  I used 400 grit sandpaper to cut it back and the result was beautiful.  Black stripes and gold tones in between.   Used a cork backing for the sandpaper and it took a while plus quite a bit of the abrasive paper.  As a side note.  Skiers use a wood tool with a thick cork working surface to apply and smooth ski wax.  I find it a handy tool for sanding.

Offline Metalshaper

  • Hero Member
  • *****
  • Posts: 610
Re: Is there a return from Iron Nitrate gone too dark ?
« Reply #24 on: December 30, 2023, 05:31:18 PM »
Jim Turpin advocates a hot water and scotch brite scrub to cut back the black of a Aqua Fortis stain. Water to keep the dust down and
I suspect it helps in flushing away build up. when your finished, the 'dry' stock should look kinda grey and and a bit ugly. Then hit it with your
 finish( or test it with a bit of water ) and you will see the grain and curl POP..

Respect Always
Metalshaper/Jonathan
« Last Edit: December 30, 2023, 05:54:04 PM by Metalshaper »