Thanks for posting that, Taylor. I suspect the metal was extremely thin to begin with, and that acidic fouling did the rest. Those plugs are real hard to clean.
That's why a flat breech flint poses the least worries: it's so simple.
T
I keep seeing comments regarding acidic fouling as a mechanism of corrosion in "black powder" guns.
The idea being that since BP contains sulfur it produces sulfur-bearing products of combustion that form acid in the bore.
No deal here. BP fouling is quite caustic. Any sufur based acid would be quickly neutralized.
The REAL culprit is chloride salts.
Pyrodex is based on 17 parts of potassium perchlorate that is found as potassium chloride after powder combustion.
Keep in mind that military cartridges were corrosive due to the use of a perchlorate, or chlorate, based primer composition. The main charge of BP or smokeless was not in itself corrosive. It was the tiny amount of chlorate/perchlorate in the primer.
Compare the two. Corrosive primers or percussion caps with a fraction of a grain of chlorate or perchlorate. Compared to a main charge that is 17 parts perchlorate.
GOEX up until 2000 left a corrosive residue. They used potassium nitrate produced by the Vicksburg Chemical Company. Bankrupt in 2000. Vicksburg used potassium chloride converting it to potassium nitrate via a reaction with nitric acid. The conversion process was not 100% effective so there was always some unreacted residual potassium chloride in the powder.
Chlorides are noted for pit corrosion. In the gun the pits deepen rapidly from the pressure pulses created during the firing of the gun.
I hasve photos here of a patent breech that did the same thing. Pits on the inside that quickly deepend and then exited on the bottom of the breech plug. The gun was stored in a horizontal position. Had it been stored vertically it would have looked just like the one in the photo.
When Col. Rains operated the Confederate Powder Works he bragged that there were no detectable levels of chlorides in the saltpeter the works purified. Other powder companies purified their saltpeter to a point where it was impossible to detect any traces of chlorides.
But today that old rule of thumb is ignored by most powder companies. Those who use the saltpeter produced in Israel have no traces of chlorides. I have not looked closely at what comes out of Chile these days.
Bill K.