I've steamed several dozen barrels. I use stove pipe, set in a pot of boiling water. Wood square on the top, with wire hooks for hanging barrel and trigger guard. All the other small parts go into the boiling water.
For the best blue quality, I only allow the metal to slightly oxidize before steaming. It usually takes a half dozen cycles to produce an old time Smith and Wesson quality blue.
Just pouring boiling water over the barrel will not do the trick. That will generally gradually turn to a brown. The metal needs to be kept in the live steam for 20 minutes to fully convert the oxidation, and 25 minutes for the boiled parts, as the boiling temperature isn't as hot as the steam.