Hex bores, i.e., 6-groove rifling, was much less common than the standard 7-groove rifling, but it was used in several states including Ohio, Indiana, and Kentucky that I am aware of. The Bardstown guns from Nelson County, Kentucky, by two of Kentucky's best makers, Jacob Rizer and David Weller, all had 6-groove rifling during the partnership period of 1815-1826, and they were considered one of the best guns made in Kentucky and very accurate. When Weller left the partnership in 1826 and moved to nearby Hardin County, he took the 6-groove rifling bench with him based on his later guns, and Rizer's shop went to 7-groove rifling on all his later rifles.
I've heard theories that an odd number of grooves makes sure a land is across from a groove, which "theoretically" pushes the patch into the groove better. If that were really true, seems odd that two of Kentucky's best gunmakers would use even-numbered rifling for eleven years right in the middle of the heyday of Kentucky's best riflemaking.
Shelby Gallien